引用文献
Electrochemical Characteristics of Metal Coated Graphite for Anodic Active Matterial of Lithium Seco
2013-03-21 14:54:28
文件类型 : PDF
文件提取码 : 应用:电池测试
简要说明 : WBCS3000多通道自动电池测试系统

Abstract: Various kinds of metals were coated on synthetic graphite in order to investigate the relationship between

film characteristics and their electrochemical performance. Gas suspension spray coating method was employed for the coating of synthetic graphite. In our experimental range, all of the metal coated synthetic graphite showed the higher capacity than that of raw material at high C-rate mainly due to decrease in impedance of passivation film. In cyclic voltammetry experiments, silver-coated and tin-coated graphite anodes found the lithium-alloy reaction. Considering smaller amount of metal coating, the most increase in discharge capacity was caused by improvement of conductivity of the electrode. When single-component metal was coated, silver-coated graphite anode exhibited the highest discharge capacity and better cycleability. Double components of silver-nickel coated active material showed the highest discharge capacity, rate capability and the best cycle performance in the range of our experiments.

Key wordsSynthetic graphite, Metal coating, Anode, Lithium secondary battery